| 000 | 02843cam a2200409 i 4500 | ||
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| 001 | on1266753357 | ||
| 003 | OCoLC | ||
| 005 | 20240726105305.0 | ||
| 008 | 210223t20202020gw a fob 000 0 eng d | ||
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_aLUN _beng _erda _epn _cLUN _dOCLCO _dVT2 _dS2H _dUKKNU _dLIP _dUAB _dOCLCQ _dNT |
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| 020 | _a3832550712 | ||
| 020 |
_a9783832550714 _q((electronic)l(electronic)ctronic) |
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| 041 | 0 |
_aeng _bger |
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| 050 | 0 | 4 |
_aQD400 _b.H484 2020 |
| 049 | _aMAIN | ||
| 100 | 1 |
_aKnoll, Daniel, _e1 |
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| 245 | 1 | 0 | _aHeterobimetallic 2.2.paracyclophane complexes and their application in photoredox catalysis /Daniel Knoll. |
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_aBerlin, Germany : _bLogos Verlag Berlin GmbH, _c(c)2020. |
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| 300 |
_a1 online resource (xiii, 212 pages) : _billustrations |
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| 336 |
_atext _btxt _2rdacontent |
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_acomputer _bc _2rdamedia |
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| 338 |
_aonline resource _bcr _2rdacarrier |
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_adata file _2rda |
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| 500 | _aAuthor's doctoral thesis, Karlsruher Institut für Technologie (KIT) -- | ||
| 504 | _a1 | ||
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_a2 _ub |
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| 520 | 0 | _aThe most important goal of current chemistry research is to provide green and sustainable routes to compounds of interest. One way of addressing this is the use of abundant and inexpensive sources of energy to drive reactions, with the prime example being visible light in photoredox catalysis. One recent promising approach is the use of heterobimetallic catalysts where two metals work in a cooperative fashion to achieve the desired transformation. However, these cooperative effects are poorly understood due to a lack of model complexes suitable for the intricate study of heterobimetallic complexes. In this work, 2.2.paracyclophane (PCP) is presented as a new platform on which to build distance-variable heterobimetallic complexes. The methods for the access to these synthetic targets are developed and investigated for their broader synthetic applicability. To demonstrate the potential of these complexes as catalysts, Au/Ru heterobimetallic complexes are evaluated regarding their performance in a dual photoredox catalytic arylative Meyer-Schuster rearrangement reaction. This reaction provides a very convenient and sustainable access α-arylated enones, an important building blocks for relevant pharmaceutical compounds. | |
| 650 | 0 | _aHeterocyclic compounds. | |
| 650 | 0 | _aCyclophanes. | |
| 655 | 1 | _aElectronic Books. | |
| 700 | 1 |
_aKarlsruher Institut für Technologie, _edegree awarding institution. |
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| 856 | 4 | 0 |
_uhttps://search.ebscohost.com/login.aspx?direct=true&scope=site&db=nlebk&db=nlabk&AN=3541181&site=eds-live&custid=s3260518 _zClick to access digital title | log in using your CIU ID number and my.ciu.edu password |
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_cOB _D _eEB _hQD _m2020 _QOL _R _x _8NFIC _2LOC |
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_c95374 _d95374 |
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_a1 _bCynthia Snell _c1 _dCynthia Snell |
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