000 | 04939cam a2200433Ki 4500 | ||
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001 | ocn864899978 | ||
003 | OCoLC | ||
005 | 20240726105441.0 | ||
008 | 131210s2013 enk ob 001 0 eng d | ||
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_aNT _beng _erda _epn _cNT _dIDEBK _dYDXCP _dCDX _dOCLCF _dMYG _dE7B _dSTF _dEBLCP _dOCLCQ _dDEBSZ |
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_a9781783263257 _q((electronic)l(electronic)ctronic) |
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050 | 0 | 4 |
_aQD116 _b.U534 2013 |
049 | _aMAIN | ||
100 | 1 |
_aCompton, R. G. _e1 |
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245 | 1 | 0 |
_aUnderstanding voltammetry : _bsimulation of electrode processes / _cby Richard G. Compton (Oxford University, UK, and University of Murcia, Spain), Eduardo Laborda (Oxford University, UK), and Kristopher R. Ward (Oxford University, UK). |
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_a[London?] : _bImperial College Press, _c(c)2013. |
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_atext _btxt _2rdacontent |
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_acomputer _bc _2rdamedia |
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_aonline resource _bcr _2rdacarrier |
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_a1. Introduction. 1.1. Electrochemical systems. 1.2. Voltammetric techniques. 1.3. Finite difference methods. 1.4. Voltammetry: a selected bibliography -- _t2. Mathematical model of an electrochemical system. 2.1. Cyclic voltammetry. 2.2. Diffusion: Fick's second law. 2.3. Boundary conditions. 2.4. Current. 2.5. Dimensionless coordinates. 2.6. Summary -- _t3. Numerical solution of the model system. 3.1. Finite differences. 3.2. Time evolution: discretising Fick's second law. 3.3. The Thomas algorithm. 3.4. Simulation procedure. 3.5. Checking results. 3.6. Performance and runtime analysis -- _t4. Diffusion-only electrochemical problems in one-dimensional systems. 4.1. Unequally spaced grids. 4.2. Finite electrode kinetics. 4.3. Unequal diffusion coefficients. 4.4. Other one-dimensional electrode geometries -- _t5. First-order chemical kinetic mechanisms. 5.1. First-order EC[symbol] mechanism: basic concepts. 5.2. First-order catalytic mechanism: coupled equation systems. 5.3. LU decomposition and extended Thomas algorithm. 5.4. First-order EC[symbol] mechanism: including a third species. 5.5. Multiple-electron transfer processes. 5.6. Heterogeneous chemical processes -- _t6. Second-order chemical kinetic mechanisms. 6.1. Second-order catalytic mechanism: the Newton-Raphson method. 6.2. Multiple-electron transfers: adaptive spatial grids. 6.3. Adsorption -- _t7. Electrochemical simulation in weakly supported media. 7.1. The Nernst-Planck-Poisson problem. 7.2. Weakly supported cyclic voltammetry and chronoamperometry -- _t8. Hydrodynamic voltammetry. 8.1. Rotating disc electrode. 8.2. Channel electrode -- _t9. Two-dimensional systems: microdisc electrodes. 9.1. Microdisc electrodes: the model. 9.2. Numerical solution. 9.3. Implementation. 9.4. Microband electrodes -- _t10. Heterogeneous surfaces. 10.1. Arrays of microdisc electrodes. 10.2. Microband arrays. 10.3. Porous electrodes. 10.4. Conclusion. |
520 | 0 | _aThis is the first textbook in the field of electrochemistry that will teach experimental electrochemists how to carry out simulation of electrode processes. Processes at both macro- and micro-electrodes are examined and the simulation of both diffusion-only and diffusion-convection processes are addressed. The simulation of processes with coupled homogeneous kinetics and at microelectrode arrays are further discussed. Over the course of the book the reader's understanding is developed to the point where they will be able to undertake and solve research-level problems. The book leads the reader through from a basic understanding of the principles underlying electrochemical simulation to the development of computer programs which describe the complex processes found in voltammetry. This is the third book in the "Understanding Voltammetry" series, published with Imperial College Press and written by the Compton group. Other books in the series include "Understanding Voltammetry", written by Richard G. Compton with Craig Banks and also "Understanding Voltammetry: Problems and Solutions" (2012) written by Richard G. Compton with Christopher Batchelor-McAuley and Edmund Dickinson. These are and continue to be successful textbooks for graduates in electrochemistry and electroanalytical studies. | |
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650 | 0 |
_aVoltammetry _vTextbooks. |
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650 | 0 |
_aElectrochemistry _vTextbooks. |
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650 | 4 |
_aElectrochemistry _xTextbooks. |
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650 | 4 | _aElectrochemistry. | |
650 | 4 |
_aVoltammetry _xTextbooks. |
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650 | 4 | _aVoltammetry. | |
655 | 1 | _aElectronic Books. | |
700 | 1 |
_aLaborda, Eduardo, _d1983- |
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700 | 1 | _aWard, Kristopher R. | |
856 | 4 | 0 |
_uhttps://search.ebscohost.com/login.aspx?direct=true&scope=site&db=nlebk&db=nlabk&AN=670627&site=eds-live&custid=s3260518 _zClick to access digital title | log in using your CIU ID number and my.ciu.edu password |
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_cOB _D _eEB _hQD. _m2013 _QOL _R _x _8NFIC _2LOC |
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_a1 _bCynthia Snell _c1 _dCynthia Snell |