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001 ocn864899978
003 OCoLC
005 20240726105441.0
008 131210s2013 enk ob 001 0 eng d
040 _aNT
_beng
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_epn
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_dIDEBK
_dYDXCP
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020 _a9781783263257
_q((electronic)l(electronic)ctronic)
050 0 4 _aQD116
_b.U534 2013
049 _aMAIN
100 1 _aCompton, R. G.
_e1
245 1 0 _aUnderstanding voltammetry :
_bsimulation of electrode processes /
_cby Richard G. Compton (Oxford University, UK, and University of Murcia, Spain), Eduardo Laborda (Oxford University, UK), and Kristopher R. Ward (Oxford University, UK).
260 _a[London?] :
_bImperial College Press,
_c(c)2013.
300 _a1 online resource.
336 _atext
_btxt
_2rdacontent
337 _acomputer
_bc
_2rdamedia
338 _aonline resource
_bcr
_2rdacarrier
347 _adata file
_2rda
504 _a2
505 0 0 _a1. Introduction. 1.1. Electrochemical systems. 1.2. Voltammetric techniques. 1.3. Finite difference methods. 1.4. Voltammetry: a selected bibliography --
_t2. Mathematical model of an electrochemical system. 2.1. Cyclic voltammetry. 2.2. Diffusion: Fick's second law. 2.3. Boundary conditions. 2.4. Current. 2.5. Dimensionless coordinates. 2.6. Summary --
_t3. Numerical solution of the model system. 3.1. Finite differences. 3.2. Time evolution: discretising Fick's second law. 3.3. The Thomas algorithm. 3.4. Simulation procedure. 3.5. Checking results. 3.6. Performance and runtime analysis --
_t4. Diffusion-only electrochemical problems in one-dimensional systems. 4.1. Unequally spaced grids. 4.2. Finite electrode kinetics. 4.3. Unequal diffusion coefficients. 4.4. Other one-dimensional electrode geometries --
_t5. First-order chemical kinetic mechanisms. 5.1. First-order EC[symbol] mechanism: basic concepts. 5.2. First-order catalytic mechanism: coupled equation systems. 5.3. LU decomposition and extended Thomas algorithm. 5.4. First-order EC[symbol] mechanism: including a third species. 5.5. Multiple-electron transfer processes. 5.6. Heterogeneous chemical processes --
_t6. Second-order chemical kinetic mechanisms. 6.1. Second-order catalytic mechanism: the Newton-Raphson method. 6.2. Multiple-electron transfers: adaptive spatial grids. 6.3. Adsorption --
_t7. Electrochemical simulation in weakly supported media. 7.1. The Nernst-Planck-Poisson problem. 7.2. Weakly supported cyclic voltammetry and chronoamperometry --
_t8. Hydrodynamic voltammetry. 8.1. Rotating disc electrode. 8.2. Channel electrode --
_t9. Two-dimensional systems: microdisc electrodes. 9.1. Microdisc electrodes: the model. 9.2. Numerical solution. 9.3. Implementation. 9.4. Microband electrodes --
_t10. Heterogeneous surfaces. 10.1. Arrays of microdisc electrodes. 10.2. Microband arrays. 10.3. Porous electrodes. 10.4. Conclusion.
520 0 _aThis is the first textbook in the field of electrochemistry that will teach experimental electrochemists how to carry out simulation of electrode processes. Processes at both macro- and micro-electrodes are examined and the simulation of both diffusion-only and diffusion-convection processes are addressed. The simulation of processes with coupled homogeneous kinetics and at microelectrode arrays are further discussed. Over the course of the book the reader's understanding is developed to the point where they will be able to undertake and solve research-level problems. The book leads the reader through from a basic understanding of the principles underlying electrochemical simulation to the development of computer programs which describe the complex processes found in voltammetry. This is the third book in the "Understanding Voltammetry" series, published with Imperial College Press and written by the Compton group. Other books in the series include "Understanding Voltammetry", written by Richard G. Compton with Craig Banks and also "Understanding Voltammetry: Problems and Solutions" (2012) written by Richard G. Compton with Christopher Batchelor-McAuley and Edmund Dickinson. These are and continue to be successful textbooks for graduates in electrochemistry and electroanalytical studies.
530 _a2
_ub
650 0 _aVoltammetry
_vTextbooks.
650 0 _aElectrochemistry
_vTextbooks.
650 4 _aElectrochemistry
_xTextbooks.
650 4 _aElectrochemistry.
650 4 _aVoltammetry
_xTextbooks.
650 4 _aVoltammetry.
655 1 _aElectronic Books.
700 1 _aLaborda, Eduardo,
_d1983-
700 1 _aWard, Kristopher R.
856 4 0 _uhttps://search.ebscohost.com/login.aspx?direct=true&scope=site&db=nlebk&db=nlabk&AN=670627&site=eds-live&custid=s3260518
_zClick to access digital title | log in using your CIU ID number and my.ciu.edu password
942 _cOB
_D
_eEB
_hQD.
_m2013
_QOL
_R
_x
_8NFIC
_2LOC
994 _a92
_bNT
999 _c100755
_d100755
902 _a1
_bCynthia Snell
_c1
_dCynthia Snell