A closer look at coordination complexes /Sandeep Kaur-Ghumaan, PHD, Associate Professor, University of Delhi, India, editor.

Includes bibliographies and index.

"Coordination chemistry plays an important role in the designing of inorganic metal complexes, materials, organo-synthesis, biological systems and catalysis. In A Closer Look at Coordination Complexes, novel and evolving developments in the field have been described. The book includes chapters on the synthesis of coordination compounds using different ligand combinations (Schiff base ligands, phosphines, thiolates, ligands with N- and S-donors and so on), biological relevance and catalytic applications of the reported metal complexes. Different aspects of metal complexes, viz. structural and coordination properties of the ligands and complexes and applications viz., asymmetric organic transformations, potential anticancer agents, antibacterial-antioxidant-antifungal properties, alkenes epoxidation, olefins polymerization, nitrogen reduction, hydrogen evolution and oxidation and mercury poisoning treatment reviewed by the authors have been delineated in the eight chapters of the book"--

Intro -- Contents -- Preface -- Chapter 1 -- Tripodal Ligands as Powerful Platforms for Designing New Catalysts -- Abstract -- 1. Introduction -- 2. Types of Tripodal Ligands -- 2.1. C3-Symmetrical Tripodal Ligands -- 2.1.1. Carbon Donor Tripodal Ligands -- 2.1.2. Nitrogen Donor Tripodal Ligands -- 2.1.3. Tripodal Oxygen and Sulphur Donor Ligands -- 2.1.4. Tripodal Phosphine and Arsine Donor Ligands -- 2.2. Non-C3-Symmetrical Tripodal Ligands -- 2.2.1. Nitrogen Donor Ligands -- 2.2.2. Nitrogen and Oxygen Mixed Donor Ligands -- 2.2.3. Nitrogen and Phosphorous Mixed Donor Ligands

2.2.4. Nitrogen and Sulphur Mixed Donor Ligands -- 2.2.5. Phosphorous and Sulphur Mixed Donor Ligands -- 3. Tripodal Ligands Containing Metal Complexes -- 3.1. Early Transition Metal Complexes -- 3.1.1. Scandium, Yttrium and Lanthanum Metal Complexes -- 3.1.2. Titanium, Zirconium and Hafnium Metal Complexes -- 3.1.3. Vanadium Metal Complexes -- 3.1.4. Chromium, Molybdenum and Tungsten Metal Complexes -- 3.1.5. Manganese Metal Complexes -- 3.2. Late Transition Metal Complexes -- 3.2.1. Iron Metal Complexes -- 3.2.1.1. Comparative Study of Iron, Cobalt and Copper Metal Complexes

3.2.2. Cobalt Metal Complexes -- 3.2.2.1. Comparative Study of Cobalt and Nickel Metal Complexes -- 3.2.3. Nickel Metal Complexes -- 3.2.4. Copper and Silver Metal Complexes -- 3.2.5. Zinc, Cadmium and Mercury Metal Complexes -- 4. Representative Examples of Metal Complexes in Catalysis -- 4.1. Nitrogen Reduction -- 4.2. Water Oxidation -- 4.3. Carbon Dioxide Reduction -- 4.4. C-H Oxidation -- 4.5. Hydroboration of Carbon Dioxide -- 4.6. Coupling Reaction -- Conclusion -- Acknowledgments -- References -- Chapter 2

Salen, Salalen and Salan Metal Complex Catalysed Asymmetric Organic Transformations -- Abstract -- 1. Introduction -- 1.1. Synthesis of Chiral Salen Ligands -- 1.2. Synthesis of Transition Metal-Salen Complexes -- 1.3. Synthesis of Metal Complexes with Chiral Salalen and Salan Ligands -- 1.4. Stereostructural Properties of Chiral Metal-Salen Complexes -- 2. Different Organic Transformations Catalysed by Transition Metal-Salen, Salalen, and Salan Complexes -- 2.1. Asymmetric Epoxidation -- 2.2. Aziridination -- 2.3. Cyclopropanation -- 2.4. Asymmetric Henry Reaction

2.5. Kinetic Resolution of Secondary Alcohols -- 2.6. Asymmetric Ring-Opening of the Epoxides -- 2.7. Hydrolytic Kinetic Resolution -- 2.8. Aminolytic Kinetic Resolution -- 2.9. Strecker Reaction -- 2.10. Hetero-Diels Alder Reaction -- 2.11. Asymmetric Hydroxylation -- 2.12. Asymmetric Oxidation of Sulfides -- 2.13. Asymmetric Oxidative Coupling -- 2.14. Cyanoformylation and Cyanosilylation of Aldehyde -- 2.15. Asymmetric Addition of Cyanide To Ketones -- 2.16. Asymmetric Mannich Addition to Ketimines -- 2.17. Asymmetric Addition of Alkynes to Aldehydes and Ketones

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