TY  - BOOK
AU  - Voronov,V.K.
AU  - Podoplelov,A.V.
TI  - Paramagnetic complexes in high resolution NMR spectroscopy /V.K. Voronov, Ikutsk State Technical University, Irkutsk, Russia, and A.V. Podoplelov, The company HTLab AG, Pfaffikon, Switzerland
T2  - Chemistry research and applications
SN  - 9781634830010
AV  - QD96 .P373 2015
PY  - 2015///
CY  - New York
PB  - Nova Science Publishers, Incorporated
KW  - Nuclear magnetic resonance spectroscopy
KW  - Electron paramagnetic resonance spectroscopy
KW  - Spectrum analysis
KW  - Chemistry, Organic
KW  - Electronic Books
N1  - 2; PARAMAGNETIC COMPLEXES IN HIGHRESOLUTION NMR SPECTROSCOPY; PARAMAGNETIC COMPLEXES IN HIGHRESOLUTION NMR SPECTROSCOPY; Library of Congress Cataloging-in-Publication Data; CONTENTS; PREFACE; Chapter 1:APPLICATION OF NMR SPECTRA OFPARAMAGNETIC SYSTEMS FOR STRUCTURALSTUDIES OF ORGANIC LIGANDS; 1.1. Nature of Hyperfine Contact Coupling in Paramagnetic Complexes; 1.2. STUDY OF SPATIAL STRUCTURE OF ORGANIC COMPOUNDS; Chapter 2:METHOD OF PARAMAGNETIC ADDITIVES; 2.1. THEORY OF THE METHOD; 2.2. PARAMAGNETIC ADDITIVES OF IRON GROUP ELEMENTS; 2.3. LANTHANIDE PARAMAGNETIC ADDITIVES; 2.4. APPLICATION OF PARAMAGNETIC COMPLEXES FOR THE NMRSPECTRA ANALYSISChapter 3:APPLICATION OF COMPLEX FORMATION PROCESSIN STRUCTURAL ST; 3.1. SPATIAL STRUCTURE OF 1-VINYLIMIDAZOLE; 3.2. COMPLEXING ABILITY AND STRUCTURE OFSI-SUBSTITUTED SILATRANES; 3.3. STRUCTURE OF METHYL THIENYL KETONE OXIME STUDIEDBY PARAMAGNETIC ADDITIVES METHOD; 3.4. PECULIARITIES OF MOLECULAR STRUCTURE OF NICKELPARAMAGNETIC COMPLEXES WITH NITROXYL RADICALS; 3.5. PECULIARITIES OF INTRAMOLECULAR EXCHANGE ANDVALENCE TAUTOMERISM IN METAL SEMI-QUINOLATES; CONCLUSION; REFERENCES; Blank Page; INDEX; 2; b
N2  - The monograph covers theoretical aspects of the method based on the analysis of NMR spectra transformed by electron-nuclear or hyperfine coupling, and provides examples of its practical application for the solution of different tasks related to structure and intramolecular dynamics of multi-electron systems. The fundamentals of NMR theory in paramagnetic systems were formulated by Blombergen, McConnell, Solomon, Berkheyn and other researchers. However, wide application of HFC specifics for the solution of diverse chemical tasks was triggered later, after the development of a method for analysi
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