Synthesis of Molybdenum and Tungsten Oxo and Imido Alkylidene NHC Complexes and Their Use in Stereoselective Ring-Opening Metathesis Polymerization

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Includes bibliographies and index.

Intro -- Danksagung -- Table of Contents -- List of Abbreviations -- Motivation -- Zusammenfassung -- Abstract -- 1 Theoretical Survey -- 1.1 Carbenes -- 1.2 Olefin Metathesis -- 1.3 Initiators for Olefin Metathesis -- 2 Results and Discussion -- 2.1 Synthesis of Trans-Isotactic Poly(Norbornene) Derivatives -- 2.2 Synthesis and Reactivity of Air-Stable Cationic Molybdenumand Tungsten Imido Alkylidene NHC Complexes -- 2.3 Synthesis and Reactivity of Cationic Molybdenum OxoAlkylidene NHC Complexes

2.4 Preparation of and Fiber Production from Fully Hydrogenated,Syndiotactic Poly(Dicyclopentadiene) through Ring-OpeningMetathesis Polymerization -- 3 Experimental -- 3.1 General -- 3.2 Equipment and Analytics -- 3.3 Chemicals Synthesized According to Literature Procedures -- 3.4 Synthesis of Trans-Isotactic Poly(Norbornene) Derivatives -- 3.5 Synthesis and Reactivity of Air-Stable Cationic Molybdenumand Tungsten Imido Alkylidene NHC Complexes -- 3.6 Synthesis and Reactivity of Cationic Molybdenum OxoAlkylidene NHC Complexes

3.7 Preparation of and Fiber Production from Fully Hydrogenated,Syndiotactic Poly(Dicyclopentadiene) through Ring-OpeningMetathesis Polymerization -- 4 References -- 5 Appendix -- 5.1 NMR Spectra -- 5.2 Single Crystal X-Ray Diffraction

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