Paramagnetic complexes in high resolution NMR spectroscopy /V.K. Voronov, Ikutsk State Technical University, Irkutsk, Russia, and A.V. Podoplelov, The company HTLab AG, Pfaffikon, Switzerland.
Voronov, V. K.
Paramagnetic complexes in high resolution NMR spectroscopy /V.K. Voronov, Ikutsk State Technical University, Irkutsk, Russia, and A.V. Podoplelov, The company HTLab AG, Pfaffikon, Switzerland. - New York : Nova Science Publishers, Incorporated, (c)2015. - 1 online resource. - Chemistry research and applications .
Includes bibliographies and index.
PARAMAGNETIC COMPLEXES IN HIGHRESOLUTION NMR SPECTROSCOPY; PARAMAGNETIC COMPLEXES IN HIGHRESOLUTION NMR SPECTROSCOPY; Library of Congress Cataloging-in-Publication Data; CONTENTS; PREFACE; Chapter 1:APPLICATION OF NMR SPECTRA OFPARAMAGNETIC SYSTEMS FOR STRUCTURALSTUDIES OF ORGANIC LIGANDS; 1.1. Nature of Hyperfine Contact Coupling in Paramagnetic Complexes; 1.2. STUDY OF SPATIAL STRUCTURE OF ORGANIC COMPOUNDS; Chapter 2:METHOD OF PARAMAGNETIC ADDITIVES; 2.1. THEORY OF THE METHOD; 2.2. PARAMAGNETIC ADDITIVES OF IRON GROUP ELEMENTS; 2.3. LANTHANIDE PARAMAGNETIC ADDITIVES. 2.4. APPLICATION OF PARAMAGNETIC COMPLEXES FOR THE NMRSPECTRA ANALYSISChapter 3:APPLICATION OF COMPLEX FORMATION PROCESSIN STRUCTURAL ST; 3.1. SPATIAL STRUCTURE OF 1-VINYLIMIDAZOLE; 3.2. COMPLEXING ABILITY AND STRUCTURE OFSI-SUBSTITUTED SILATRANES; 3.3. STRUCTURE OF METHYL THIENYL KETONE OXIME STUDIEDBY PARAMAGNETIC ADDITIVES METHOD; 3.4. PECULIARITIES OF MOLECULAR STRUCTURE OF NICKELPARAMAGNETIC COMPLEXES WITH NITROXYL RADICALS; 3.5. PECULIARITIES OF INTRAMOLECULAR EXCHANGE ANDVALENCE TAUTOMERISM IN METAL SEMI-QUINOLATES; CONCLUSION; REFERENCES; Blank Page; INDEX.
The monograph covers theoretical aspects of the method based on the analysis of NMR spectra transformed by electron-nuclear or hyperfine coupling, and provides examples of its practical application for the solution of different tasks related to structure and intramolecular dynamics of multi-electron systems. The fundamentals of NMR theory in paramagnetic systems were formulated by Blombergen, McConnell, Solomon, Berkheyn and other researchers. However, wide application of HFC specifics for the solution of diverse chemical tasks was triggered later, after the development of a method for analysi.
9781634830010
2019722677
Nuclear magnetic resonance spectroscopy.
Electron paramagnetic resonance spectroscopy.
Spectrum analysis.
Chemistry, Organic.
Electronic Books.
QD96 / .P373 2015
Paramagnetic complexes in high resolution NMR spectroscopy /V.K. Voronov, Ikutsk State Technical University, Irkutsk, Russia, and A.V. Podoplelov, The company HTLab AG, Pfaffikon, Switzerland. - New York : Nova Science Publishers, Incorporated, (c)2015. - 1 online resource. - Chemistry research and applications .
Includes bibliographies and index.
PARAMAGNETIC COMPLEXES IN HIGHRESOLUTION NMR SPECTROSCOPY; PARAMAGNETIC COMPLEXES IN HIGHRESOLUTION NMR SPECTROSCOPY; Library of Congress Cataloging-in-Publication Data; CONTENTS; PREFACE; Chapter 1:APPLICATION OF NMR SPECTRA OFPARAMAGNETIC SYSTEMS FOR STRUCTURALSTUDIES OF ORGANIC LIGANDS; 1.1. Nature of Hyperfine Contact Coupling in Paramagnetic Complexes; 1.2. STUDY OF SPATIAL STRUCTURE OF ORGANIC COMPOUNDS; Chapter 2:METHOD OF PARAMAGNETIC ADDITIVES; 2.1. THEORY OF THE METHOD; 2.2. PARAMAGNETIC ADDITIVES OF IRON GROUP ELEMENTS; 2.3. LANTHANIDE PARAMAGNETIC ADDITIVES. 2.4. APPLICATION OF PARAMAGNETIC COMPLEXES FOR THE NMRSPECTRA ANALYSISChapter 3:APPLICATION OF COMPLEX FORMATION PROCESSIN STRUCTURAL ST; 3.1. SPATIAL STRUCTURE OF 1-VINYLIMIDAZOLE; 3.2. COMPLEXING ABILITY AND STRUCTURE OFSI-SUBSTITUTED SILATRANES; 3.3. STRUCTURE OF METHYL THIENYL KETONE OXIME STUDIEDBY PARAMAGNETIC ADDITIVES METHOD; 3.4. PECULIARITIES OF MOLECULAR STRUCTURE OF NICKELPARAMAGNETIC COMPLEXES WITH NITROXYL RADICALS; 3.5. PECULIARITIES OF INTRAMOLECULAR EXCHANGE ANDVALENCE TAUTOMERISM IN METAL SEMI-QUINOLATES; CONCLUSION; REFERENCES; Blank Page; INDEX.
The monograph covers theoretical aspects of the method based on the analysis of NMR spectra transformed by electron-nuclear or hyperfine coupling, and provides examples of its practical application for the solution of different tasks related to structure and intramolecular dynamics of multi-electron systems. The fundamentals of NMR theory in paramagnetic systems were formulated by Blombergen, McConnell, Solomon, Berkheyn and other researchers. However, wide application of HFC specifics for the solution of diverse chemical tasks was triggered later, after the development of a method for analysi.
9781634830010
2019722677
Nuclear magnetic resonance spectroscopy.
Electron paramagnetic resonance spectroscopy.
Spectrum analysis.
Chemistry, Organic.
Electronic Books.
QD96 / .P373 2015